Come on guys, give the man a break. If he wants to fry the H100 who are we to judge? It's in a way like overclocking the cooler...
Back on topic, the +12V rail is DC and you'd need say 14V of DC - the thing is one can't simply turn DC voltage from one level to the other like you can with AC, on AC a simple transformer suffices. On DC you need something more complex like a buck/boost or a DC/DC which can be expensive and/or complicated if you wanna build it yourself. There could be ICs that do exactly what you want, but you'd still have to filter the 14V side. This is the clean and proper way to do it, but it's also complicated and/or expensive.
The easier way as I see it is to hack the motherboard ATX connector. Here are some examples of voltages that one can take from a regular MOLEX HDD connector: +12V between +12V and GND, +7V between +12 and +5V (12-5), etc.
Here you can find the pinout for the ATX connector, it is the only one that has negative voltages:
http://pinouts.ru/Power/atxpower_pinout.shtml
The idea is that for more than +12V you'd need to power between the +12V rail and minus-something so that for example H100voltage=+12V-(-5) ==17V. There's not much granularity, ATX plugs only have -5V and -12V and they can't supply much current anyway. 13.5 is impossible, you can have 17V between +12 and -5 or maybe +24V between + and -12V. However keep this in mind: -something rails aren't meant to power much of anything, so it's likely they won't be able to even if you hardwire them; also you need to hack the ATX plug or cut for example the -5V wire to insert a "Y" - so if you could short your PSU and fry everything.
Well anyway you tackle it, keep us posted. It could be interesting to see if something works
