You've got a really nice 800w unit. It should handle the SLI fine. Why not throw the second card in, and try it out? See if the gain really is worth it, and see what the temps are like.
OK got my SLI cable on the way from amazon. Was not really sure about that PSU since I read a real long thread about a guy with a 750 PSU asking about SLI. Most of the recommendations said no, but I had no idea mine was a good brand.