OK thanks for that - looks like I was on the right track, and it seems that high-impedance cans deliver a smoother signal with less distortion, but require higher voltages.
Question: would you recommend for a PC output, high impedance or low? Looking
here, I see that the audio chip on my motherboard is capable of outputting up to 1.5V (actually my chip is a Realtek ALC887, not an ALC880 in the article, but I assume the output will be similar).
Currently I'm using Sennheiser HD200s which have a 64Ohm impedance. How high do you think I could go without losing volume? Is 1.5V enough to drive a 250Ohm headphone?